MEASUREMENT OF THE AMPLITUDE OF A SPINODAL

被引:31
作者
HETHERINGTON, MG [1 ]
HYDE, JM [1 ]
MILLER, MK [1 ]
SMITH, GDW [1 ]
机构
[1] OAK RIDGE NATL LAB, DIV MET & CERAM, OAK RIDGE, TN 37831 USA
关键词
D O I
10.1016/0039-6028(91)90431-Q
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
One of the strengths of the atom-probe is its ability to measure the amplitude of composition fluctuations on a very fine scale. In previous papers, calculation of the amplitude of a spinodal using a sinusoidal composition distribution has been reported. In this paper, a comparison is made between the fit of experimental data from the atom-probe to a sinusoidal distribution and also to the amplitude of the composition variations expected from non-linear theories of the spinodal decomposition. It is shown that, in general, the Langer, Bar-on and Miller (LBM) non-linear theory provides better fits to the data. In particular, the non-linear theory is able to describe the asymmetry of the distribution functions for mean compositions far from the critical composition.
引用
收藏
页码:304 / 314
页数:11
相关论文
共 11 条
[1]   STATISTICAL-ANALYSIS OF ATOM-PROBE DATA .2. THEORETICAL FREQUENCY-DISTRIBUTIONS FOR PERIODIC FLUCTUATIONS AND SOME APPLICATIONS [J].
AUGER, P ;
MENAND, A ;
BLAVETTE, D .
JOURNAL DE PHYSIQUE, 1988, 49 (C-6) :439-444
[2]   ON SPINODAL DECOMPOSITION [J].
CAHN, JW .
ACTA METALLURGICA, 1961, 9 (09) :795-801
[3]   FREE ENERGY OF A NONUNIFORM SYSTEM .1. INTERFACIAL FREE ENERGY [J].
CAHN, JW ;
HILLIARD, JE .
JOURNAL OF CHEMICAL PHYSICS, 1958, 28 (02) :258-267
[4]   LATER STAGES OF SPINODAL DECOMPOSITION AND BEGINNINGS OF PARTICLE COARSENING [J].
CAHN, JW .
ACTA METALLURGICA, 1966, 14 (12) :1685-+
[5]  
CEREZO A, 37TH INT FIELD EM S
[6]   BROWNIAN MOTION IN SPINODAL DECOMPOSITION [J].
COOK, HE .
ACTA METALLURGICA, 1970, 18 (03) :297-+
[7]   THE CHARACTERIZATION OF SPINODAL STRUCTURES IN DUPLEX CF3 STEELS [J].
GODFREY, TJ ;
HETHERINGTON, MG ;
SASSEN, JM ;
SMITH, GDW .
JOURNAL DE PHYSIQUE, 1988, 49 (C-6) :421-426
[8]  
HETHERINGTON MG, 1989, J PHYS-PARIS, V50, pC8535
[9]   A SOLID-SOLUTION MODEL FOR INHOMOGENEOUS SYSTEMS [J].
HILLERT, M .
ACTA METALLURGICA, 1961, 9 (06) :525-535
[10]   NEW COMPUTATIONAL METHOD IN THEORY OF SPINODAL DECOMPOSITION [J].
LANGER, JS ;
BARON, M ;
MILLER, HD .
PHYSICAL REVIEW A, 1975, 11 (04) :1417-1429