ON THE ADSORPTION OF CO2 BY MOLECULAR-SIEVE CARBONS - VOLUMETRIC AND GRAVIMETRIC STUDIES

被引：48

作者：

NAKASHIMA, M ^{[1
]}

SHIMADA, S ^{[1
]}

INAGAKI, M ^{[1
]}

CENTENO, TA ^{[1
]}

机构：

[1] UNIV NEUCHATEL,DEPT CHEM,CH-2000 NEUCHATEL,SWITZERLAND

来源：

CARBON | 1995年 / 33卷 / 09期

关键词：

MOLECULAR SIEVE CARBONS; HEAT TREATMENT; CO2; ADSORPTION; CALORIMETRY;

D O I：

10.1016/0008-6223(95)00077-Q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two microporous carbons, derived from the same phenolic resin at 700 and 1000 degrees C, were investigated by volumetric and gravimetric adsorption of CO2 and N-2 at different temperatures. The combination with immersion calorimetry into liquids of different molecular sizes reveals the presence of constrictions near 0.4-0.45 nm leading into relatively large micropores. The size of the constrictions and the micropore volume are smaller for the solid prepared at 1000 degrees C.

引用

页码：1301 / 1306

页数：6

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