PHOSPHORYL TRANSFER PROMOTED BY NITRILES IN PRESENCE OF HIGH REACTIVE HALIDES

被引：4

作者：

CLARK, VM

HUTCHINS.DW

VAREY, PF

机构：

[1] School of Molecular Sciences, University of Warwick

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 01期

关键词：

D O I：

10.1039/j39690000074

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Nitriles, e.g. acetonitrile and benzonitrile slowly react at elevated temperatures with mono-substituted phosphoric acids to give sym-pyrophosphates. Prior addition of a highly reactive halide, e.g. a chloromethyl ether or thioether, gives rise to a much more effective phosphoryl transfer. Both anhydrides and esters can be generated in this way.

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页码：74 / &

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