INTENSITY PERTURBATIONS DUE TO CONFIGURATION INTERACTION OBSERVED IN ELECTRON ENERGY-LOSS SPECTRUM OF N2

被引：100

作者：

GEIGER, J

SCHRODER, B

机构：

[1] I. Physikalisches Institut, Technischen Universität Berlin, Berlin

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 50卷 / 01期

关键词：

D O I：

10.1063/1.1670870

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The electron energy-loss spectrum of 25-keV electrons in molecular nitrogen has been re-investigated in the 12.5-14.9 eV energy-loss range with improved energy resolution of 10 meV. The band intensities of the b and b′ progressions, which consist of the bands. j, b, m, p, q, and b′, g, f, r, s, t as recently turned out, exhibit strong perturbations due to configuration interaction with the c and c′ state, respectively. The disturbed intensity in the progressions is quite analogous to the one in the two-electron excitation region of helium. Intensity perturbations in the o series, if any, should be very weak.

引用

页码：7 / &

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