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PHASE-EQUILIBRIA AND CHEMICAL-POTENTIALS IN INFINITE DILUTION OF NONIDEAL FLUID MIXTURES FROM PERTURBATION-THEORY

被引：3
作者：
SHUKLA, KP
机构：
[1] Department of Chemical Engineering, George R. Brown School of Engineering, Rice University, Houston
来源：
FLUID PHASE EQUILIBRIA | 1991年 / 67卷
关键词：
D O I：
10.1016/0378-3812(91)90053-A
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
A recently developed first-order hard sphere perturbation theory, in combination with the random phase approximation, is applied to calculate phase equilibria and chemical potentials in infinite dilution of several simple binary fluid mixtures. Results are reported for Lennard-Jones mixtures in which the components differ significantly in their molecular size and energy parameters. Detailed comparisons of theoretical predictions with recent simulation results show the perturbation theory to be highly reliable in varying non-ideal conditions.
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页码：151 / 171
页数：21
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