APPLICATION OF AN EOS CHAIN ASSOCIATION THEORY TO THE CALCULATION OF THERMODYNAMIC PROPERTIES OF (ALKANE+1-ALKANOL) MIXTURES

被引：26

作者：

DEITERS, UK

机构：

[1] Ruhr-Universität Bochum, D-4630 Bochum 1

来源：

FLUID PHASE EQUILIBRIA | 1993年 / 89卷 / 01期

关键词：

THEORY; EQUATION OF STATE; CHAIN ASSOCIATION;

D O I：

10.1016/0378-3812(93)85052-N

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Chain association theory has been extended to account for molecular volume changes during the formation of hydrogen bonds. A non-cubic equation of state in connection with this chain association theory is used to correlate vapour-liquid equilibria of four test mixtures: hexane + methanol, hexane + ethanol, hexane + 1-hexanol, and decane + 1-butanol. Calculated excess enthalpies and excess volumes are in good agreement with experimental data.

引用

页码：229 / 242

页数：14

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