DOUBLE SULFUR CARBON BOND-CLEAVAGE OF A DITHIOCARBAMATE LIGAND AT A MOLYBDENUM(VI) CENTER - SYNTHESIS AND X-RAY STRUCTURE OF THE DISULFUR COMPLEX [MO(NPH)(S2)(EDTC)2] (EDTC = S2CNET2)

被引：17

作者：

COFFEY, TA ^{[1
]}

FORSTER, GD ^{[1
]}

HOGARTH, G ^{[1
]}

机构：

[1] UNIV LONDON UNIV COLL,DEPT CHEM,20 GORDON ST,LONDON WC1H 0AJ,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 19期

关键词：

D O I：

10.1039/c39930001524

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of 1 equiv. of PhNCO with [MoO2(edtc)2] leads to the isolation of [Mo(NPh)(S2)(edtc)2] formed as a result of oxo substitution and a double sulfur-carbon bond cleavage of the dithiocarbamate; a second product is dimeric (MoO(edtc)(mu-NPh)]2.

引用

页码：1524 / 1525

页数：2

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