METATHESIS OF SILICON-CONTAINING OLEFINS .9. SYNTHESIS OF 1-(TRIMETHYLSILYL)-1-ALKENES BY OLEFIN METATHESIS

被引：14

作者：

FOLTYNOWICZ, Z ^{[1
]}

PIETRASZUK, C ^{[1
]}

MARCINIEC, B ^{[1
]}

机构：

[1] ADAM MICKIEWICZ UNIV POZNAN,FAC CHEM,PL-60780 POZNAN,POLAND

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 1993年 / 7卷 / 07期

关键词：

SILYL ALKENES; PREPARATION; RUTHENIUM CATALYST;

D O I：

10.1002/aoc.590070714

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

1-(Trimethylsilyl)-1-alkenes of general formula CH3(CH2)nCH=CHSi(CH3)3, where n = 3-15, have been prepared by a novel method, viz. by an effective cross-metathesis of vinyltrimethylsilane with 1-alkenes catalyzed by RuCl2(PPh3)3. Excess of 1-alkene in the reaction mixture gave 1-(trimethylsilyl)-l-alkenes in good yields of up to 60% (in terms of vinylsilane). The products were identified by NMR spectroscopic (H-1, C-13 NMR) and GC MS methods.

引用

页码：539 / 541

页数：3

共 13 条

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