ISOMERIZATION OF CYCLOOCTENE AND CYCLODODECENE OXIDES CATALYZED BY SOLID ACIDS AND BASES

被引：3

作者：

ARATA, K

NAKAMURA, H

NAKAMURA, Y

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1994年 / 67卷 / 08期

关键词：

D O I：

10.1246/bcsj.67.2351

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title reactions were carried out over seven catalysts. From cyclooctene oxide a large amount of 7-octenal was formed together with 3-cycloocten-1-ol over SiO2-Al2O3 and SiO2-TiO2, 3-cycloocten-1-ol over solid H3PO4, and cyclooctanone over FeSO4. Most catalysts except for NiSO4, Al2O3, and TiO2-ZrO2 produced 1,3-cyclododecadiene, cyclododecanone, and 2-cyclododecen-1-ol uniformly from cyclododecene oxide. Allylic alcohols were preferentially given by Al2O3 and TiO2-ZrO2.

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页码：2351 / 2353

页数：3

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