TRIMETHYLPHOSPHINE AND TRIMETHYLAMINE - REARRANGEMENTS COMMON TO THEIR MASS SPECTRA

被引:13
作者
GILLIS, RG
LONG, GJ
机构
[1] Australian Defence Scientific Service, Defence Standards Laboratories, Maribyrnong, Victoria
来源
ORGANIC MASS SPECTROMETRY | 1969年 / 2卷 / 12期
关键词
D O I
10.1002/oms.1210021212
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Metastable ions confirm the rearrangement of the [M  H]+ ion from trimethylphosphine and trimethylamine to give [C3H5]+. Two‐carbon fragments are seen but their origin is indeterminate. Extensive loss of H2 occurs, confirmed by metastable ions, but not of CH2. Copyright © 1969 John Wiley & Sons, Ltd.
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页码:1315 / &
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