SYNTHESIS AND X-RAY STRUCTURAL-ANALYSIS OF AIRSTABLE BIS[3-(DIMETHYLAMINO)PROPYL]INDIUM DERIVATIVES

被引：30

作者：

SCHUMANN, H

GORLITZ, FH

SEUSS, TD

WASSERMANN, W

机构：

[1] Institut für Anorganische und Analytische Chemie, Technischen Universität Berlin, Berlin, W-1000

来源：

CHEMISCHE BERICHTE-RECUEIL | 1992年 / 125卷 / 01期

关键词：

INDIUM; PENTACOORDINATED ORGANO COMPOUNDS; INTRAMOLECULAR BASE STABILIZATION;

D O I：

10.1002/cber.19921250102

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pentacoordinate, intramolecularly base-stabilized organoindium compounds [Me2N(CH2)3]2InBr (1), [Me2N(CH2)3]2InO2CCF3 (2) and [Me2N(CH2)3]2InOC6F5 (3) as well as [Me2N(CH2)3]2InC2H5 (4), [Me2N(CH2)3]2In(i-C3II7) (5), and [Me2N(CH2)3]2In(t-C4II9) (6) have been prepared by the reaction of indium tribromide with 3-(dimethylamino)propyllithium and of bis[3-(dimethylamino)propyl]indium chloride with NaO2CCF3, LiOC6F5, C2II5MgBr, i-C3H2MgBr, and t-C4II9Li, respectively. The H-1-, C-13-, F-19-NMR and mass spectra of the new compounds as well as the single-crystal X-ray structure analysis of 1 are described and discussed.

引用

页码：3 / 7

页数：5

共 32 条

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