EPOXY-RESIN COPOLYMER WITH ZERO SHRINKAGE .2. THERMAL AND MECHANICAL-PROPERTIES

被引:11
作者
HE, PS
ZHOU, ZQ
机构
[1] Department of Materials Science and Engineering, University of Science and Technology of China, Anhui
关键词
D O I
10.1007/BF01184973
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Thermal gravimetry, differential scanning calorimetry, stress-strain and dynamic mechanical testing were performed for pure epoxy resin and epoxy copolymers. Shrinkage, equal density or expansion was obtained by copolymerizing epoxy resin with various amounts of the expanding monomer norbornene spiro-orthocarbonate (NSOC). The glass-transition temperature, thermal-degradation temperature and fracture strength decreased with the introduction of NSOC, indicating that the effect of chain structure on the physical properties of epoxy copolymer was more than that of volume expansion arising from the ring-opening polymerization of expanding monomer NSOC.
引用
收藏
页码:3792 / 3796
页数:5
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