[2,2'-DIMETHYL-6,6'-BIS(DIPHENYLPHOSPHINO)BIPHENYL](TRIPHENYLPHOSPHINE)-DICHLORORUTHENIUM(II) - AN ENANTIOSELECTIVE CATALYST FOR THE HYDROGENATION OF DIKETONES

被引：38

作者：

MEZZETTI, A

CONSIGLIO, G

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 23期

关键词：

D O I：

10.1039/c39910001675

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The novel species [RuCl2(PPh3){(S)-biphemp}] 1 and [RuH(eta-2-BH4)(PPh3){(S)-biphemp}] 3 [biphemp = 2,2'-dimethyl-6,6'-bis(diphenylphosphino)biphenyl] have been synthesized; 1 has a labile triphenylphosphine ligand and is a very active and enantioselective catalyst for the mono- or bis-hydrogenation of pentane-2,4-dione.

引用

页码：1675 / 1677

页数：3

共 22 条

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