FACILE AERIAL OXIDATION OF A PORPHYRIN .18. N-ALKYLATION OF THE OXIDIZED PRODUCT DERIVED FROM MESO-TETRAKIS(3,5-DI-T-BUTYL-4-HYDROXYPHENYL)PORPHYRIN

被引：32

作者：

MILGROM, LR

HILL, JP

YAHIOGLU, G

机构：

[1] Department of Chemistry, Brunel University, Uxbridge, Middlesex

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 1995年 / 32卷 / 01期

关键词：

D O I：

10.1002/jhet.5570320117

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In basic solutions, the oxidised porphyrin 2 readily undergoes macrocyclic N-alkylation, with up to four bulky alkyl groups, including decyl and substituted benzyl moieties, being accomodated: an argument is presented to show that N-di-alkylation occurs on opposite nitrogen atoms, on the same side of the macrocycle.

引用

页码：97 / 101

页数：5

共 18 条

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