PALLADIUM-CATALYZED SUBSTITUTION OF ESTERS OF NAPHTHYLMETHANOLS, 1-NAPHTHYLETHANOLS, AND ANALOGS BY SODIUM DIMETHYL MALONATE - STEREOSELECTIVE SYNTHESIS FROM ENANTIOMERICALLY PURE SUBSTRATES

被引：83

作者：

LEGROS, JY

TOFFANO, M

FIAUD, JC

机构：

[1] Laboratoire de Synthèse Asymétrique Associé au C.N.R.S. (URA no 1497), Institut de Chimie Moléculaire d'Orsay, Université de Paris-Sud, 91405 Orsay

来源：

TETRAHEDRON | 1995年 / 51卷 / 11期

关键词：

D O I：

10.1016/0040-4020(95)00061-C

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The palladium-catalyzed substitution of carbonates of the titled alcohols was performed at lower temperature than the previously reported reaction of the corresponding acetates. The use of enantiomerically pure carbonates gave substitution products with overall retention of the configuration (up to 97%).

引用

页码：3235 / 3246

页数：12

共 29 条

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