REACTION BETWEEN COBALT(3) AND SILVER(1) PERCHLORATES IN PERCHLORIC ACID MEDIA

被引：7

作者：

COWLEY, DJ

MASON, D

SUTCLIFF.LH

机构：

[1] Donnan Chemical Laboratories, The University, Liverpool

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1969年 / 31卷 / 06期

关键词：

D O I：

10.1016/0022-1902(69)80386-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several values of the equilibrium constant (K2) for the reaction Co(III) + Ag(I) ⇌ Co(II)+ Ag(II) have been obtained and are discussed. The value of K2 is concluded to be (3 ± 2) × 10-2 at 25°C. The thermodynamic parameters for this equilibrium are calculated to be: ΔG° = + 2·08 kcal mole-1; ΔH° = (0·0 ± 2·0) kcal mole-1 and ΔS° = -7·0 cal mole-1 deg-1. © 1969.

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页码：1709 / &

相关论文

共 9 条

[1]

DIABLER H, 1964, J PHYS CHEM, V68, P65

[2] EFFECT OF AG(1) IONS ON RATE OF ELECTRON TRANSFER BETWEEN AQUEOUS CO(2) AND CO(3) IONS [J].

HAUGEN, JA ;

HABIB, HS .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1968, 30 (01) :225-&

[3] KINETICS OF SOME OXIDATION-REDUCTION REACTIONS INVOLVING SILVER(2) [J].

HUCHITAL, DH ;

SUTIN, N ;

WARNQVIS.B .

INORGANIC CHEMISTRY, 1967, 6 (04) :838-&

[4]

JOHNSON DA, 1964, J CHEM SOC, P3490

[5] SILVER(I) CATALYZED OXIDATION OF CHROMIUM)3) BY COBALT)3) IN PERCHLORIC ACID MEDIA [J].

KIRWIN, JB ;

PROLL, PJ ;

SUTCLIFFE, LH .

TRANSACTIONS OF THE FARADAY SOCIETY, 1964, 60 (4931) :119-&

[6] REACTION BETWEEN COBALT(III) AND SILVER(I) PERCHLORATES IN PERCHLORIC ACID MEDIA [J].

KIRWIN, JB ;

PROLL, PJ ;

SUTCLIFFE, LH ;

PEAT, FD .

JOURNAL OF PHYSICAL CHEMISTRY, 1963, 67 (11) :2288-&

[7] A KINETIC AND SPECTROPHOTOMETRIC EXAMINATION OF SILVER(2+ IN PERCHLORATE MEDIA [J].

KIRWIN, JB ;

PEAT, FD ;

SUTCLIFFE, LH ;

PROLL, PJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1963, 67 (08) :1617-&

[8] PARAMAGNETIC RESONANCE OF SOME SILVER (II) COMPOUNDS [J].

MCMILLAN, JA ;

SMALLER, B .

JOURNAL OF CHEMICAL PHYSICS, 1961, 35 (05) :1698-&

[9] Argentic salts in acid solution. V. Oxidation potentials, equilibria with higher silver oxides, and formation of nitrate complexes [J].

Noyes, AA ;

De Vault, D ;

Coryell, CD ;

Deahl, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1937, 59 :1326-1337