RUTHENIUM COMPLEXES WITH DIAZADIENES .11. MONONUCLEAR BIS(DIAZADIENE)RUTHENIUM(O) COMPLEXES AND THE COUPLING OF BUTADIENE TO A DIAZADIENE SYSTEM

被引：11

作者：

ROSENBERGER, V ^{[1
]}

DIECK, HT ^{[1
]}

机构：

[1] UNIV HAMBURG,INST ANORGAN & ANGEW CHEM,MARTIN LUTHER KING PL 6,W-2000 HAMBURG 13,GERMANY

来源：

CHEMISCHE BERICHTE | 1990年 / 123卷 / 01期

关键词：

Diazadienes/Carbon–carbon coupling/Ruthenium(0) complexes/Ethylene complexes;

D O I：

10.1002/cber.19901230117

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Complexes (dad)2RuCl2 (1) (dad = diazadiene, RN = CR'– CR'=NR) are reduced to (dad)2Ru (2) which react with L = CO or ethylene to give (dad)2RuL (3,5). Reduction of 1b ( R' = H) with magnesium–butadiene or reaction of 2b with butadiene leads to a new type of C–C coupling of butadiene to one of the diazadiene ligands (6b). Addition of CO induces a rearrangement to 7b by a hydride shift. Copyright © 1990 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

引用

页码：83 / 85

页数：3

共 28 条

[1] REGIOSELECTIVE AND STEREOSELECTIVE HYDROSILYLATION OF ISOPRENE WITH RHODIUM(I) AND RUTHENIUM(II) COMPLEXES OF UNSATURATED N-CONTAINING CONTROLLING LIGANDS
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[8] DIECK HT, 1985, ANGEW CHEM INT EDIT, V24, P781
[9] DIAZADIENES AS CONTROLLING LIGANDS IN CATALYSIS .5. SYNTHESIS OF CHIRAL DIAZADIENES R]-N=CR'-CR'=N-R
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