STEREOSELECTIVE REDUCTION OF ACYCLIC ALPHA-BROMO ESTERS

被引：72

作者：

GUINDON, Y ^{[1
]}

YOAKIM, C ^{[1
]}

LEMIEUX, R ^{[1
]}

BOISVERT, L ^{[1
]}

DELORME, D ^{[1
]}

LAVALLEE, JF ^{[1
]}

机构：

[1] UNIV MONTREAL,DEPT CHEM,MONTREAL H3C 3J7,QUEBEC,CANADA

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 20期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/0040-4039(90)80163-G

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Radical-based reduction of β-methoxy- or β-fluoro-α-bromo esters could be achieved with good stereoselection at low temperatures. A systematic evaluation of this reaction is presented and possible transition state models are discussed. © 1990.

引用

页码：2845 / 2848

页数：4

共 13 条

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[10] FREE-RADICAL CYCLIZATIONS - APPLICATION TO THE TOTAL SYNTHESIS OF DL-PLEUROTIN AND DL-DIHYDROPLEUROTIN ACID
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (19) : 7507 - 7519

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