LIFETIME RECOVERY FOR SPECIES PARTICIPATING IN COMPLEX KINETICS - APPLICATION TO THE REVERSIBLE EXCIMER

被引：7

作者：

BERBERANSANTOS, MN

FARINHA, JP

MARTINHO, JMG

DUHAMEL, J

WINNIK, MA

机构：

[1] UNIV TORONTO,ERINDALE COLL,TORONTO M5S 1A1,ONTARIO,CANADA

[2] UNIV TORONTO,LASH MILLER CHEM LABS,DEPT CHEM,TORONTO M5S 1A1,ONTARIO,CANADA

来源：

CHEMICAL PHYSICS LETTERS | 1992年 / 189卷 / 4-5期

关键词：

D O I：

10.1016/0009-2614(92)85210-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new method for the determination of intrinsic lifetimes of excited species participating in a complex mechanism is presented. This method is independent of the mechanism itself, and only requires that the interacting species maintain their indentity and exist in a known number. The method is applied to the determination of the excimer lifetime of pyrene in cyclohexanol from 25 to 85-degrees-C. An activation energy of 12 +/- 1 kJ mol-1 is calculated from the reciprocal excimer lifetime Arrhenius plot.

引用

页码：328 / 332

页数：5

共 15 条

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