POLY[TRANS-BIS(3,4-ETHYLENEDIOXYTHIOPHENE)VINYLENE] - A LOW-BAND-GAP POLYMER WITH RAPID REDOX SWITCHING CAPABILITIES BETWEEN CONDUCTING TRANSMISSIVE AND INSULATING ABSORPTIVE STATES

被引:54
作者
SOTZING, GA [1 ]
REYNOLDS, JR [1 ]
机构
[1] UNIV FLORIDA,CTR MACROMOLEC SCI & ENGN,DEPT CHEM,GAINESVILLE,FL 32611
关键词
D O I
10.1039/c39950000703
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
trans-Bis(3,4-ethylenedioxythiophene)vinylene is synthesized and electrochemically polymerized to give poly[ trans-bis(3,4-ethylenedioxythiophene)vinylene] (PBEDOT-V) which exhibits a band gap of 1.4 eV and can be rapidly switched between insulating deep purple absorptive and highly conducting light blue transmissive states.
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收藏
页码:703 / 704
页数:2
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