POLY[TRANS-BIS(3,4-ETHYLENEDIOXYTHIOPHENE)VINYLENE] - A LOW-BAND-GAP POLYMER WITH RAPID REDOX SWITCHING CAPABILITIES BETWEEN CONDUCTING TRANSMISSIVE AND INSULATING ABSORPTIVE STATES

被引：54

作者：

SOTZING, GA ^{[1
]}

REYNOLDS, JR ^{[1
]}

机构：

[1] UNIV FLORIDA,CTR MACROMOLEC SCI & ENGN,DEPT CHEM,GAINESVILLE,FL 32611

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 06期

关键词：

D O I：

10.1039/c39950000703

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

trans-Bis(3,4-ethylenedioxythiophene)vinylene is synthesized and electrochemically polymerized to give poly[ trans-bis(3,4-ethylenedioxythiophene)vinylene] (PBEDOT-V) which exhibits a band gap of 1.4 eV and can be rapidly switched between insulating deep purple absorptive and highly conducting light blue transmissive states.

引用

页码：703 / 704

页数：2

共 12 条

[1] SYNTHESIS AND CHARACTERIZATION OF ALKYL-SUBSTITUTED POLY(THIOPHENE-2,5-DIYLVINYLENE)S
BOLOGNESI, A
CATELLANI, M
PORZIO, W
SPERONI, F
GALARINI, R
MUSCO, A
PONTELLINI, R
[J]. POLYMER, 1993, 34 (19) : 4150 - 4155
[2] ELECTROCHEMICAL AND SPECTROSCOPIC CHARACTERIZATION OF POLYALKYLENEDIOXYTHIOPHENES
DIETRICH, M
HEINZE, J
HEYWANG, G
JONAS, F
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1994, 369 (1-2): : 87 - 92
[3] EEVERS W, 1994, POLYMER, V35, P4873
[4] LOW BAND-GAP CONJUGATED POLYMERS - POLY (THIENYLENE VINYLENE) AND POLY (SUBSTITUTED THIENYLENE VINYLENES)
JEN, KY
HAN, CC
ELSENBAUMER, RL
[J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1990, 186 : 211 - 222
[5] HIGHLY-CONDUCTING, POLY(2,5-THIENYLENE VINYLENE) PREPARED VIA A SOLUBLE PRECURSOR POLYMER
JEN, KY
MAXFIELD, M
SHACKLETTE, LW
ELSENBAUMER, RL
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (04) : 309 - 311
[6] JEN KY, 1988, J CHEM SOC CHEM COMM, P217
[7] Jonas F., 1991, U.S. Patent, Patent No. [5035926, 5035926A]
[8] THE ELECTRONIC AND ELECTROCHEMICAL PROPERTIES OF POLY(ISOTHIANAPHTHENE)
KOBAYASHI, M
COLANERI, N
BOYSEL, M
WUDL, F
HEEGER, AJ
[J]. JOURNAL OF CHEMICAL PHYSICS, 1985, 82 (12) : 5717 - 5723
[9] ELECTROCHEMICAL SYNTHESIS AND OPTICAL ANALYSIS OF POLY[(2,2'-DITHIENYL)-5,5'-DIYLVINYLENE]
MARTINEZ, M
REYNOLDS, JR
BASAK, S
BLACK, DA
MARYNICK, DS
POMERANTZ, M
[J]. JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1988, 26 (04) : 911 - 920
[10] MRASE I, 1987, POLYM COMMUN, P277

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