ROTO-TRANSLATIONAL MOTION IN LIQUID WATER AND ITS STRUCTURAL IMPLICATION

被引：36

作者：

SVISHCHEV, IM

KUSALIK, PG

机构：

[1] Department of Chemistry, Dalhousie University, Halifax

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 215卷 / 06期

关键词：

D O I：

10.1016/0009-2614(93)89362-L

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The two nonvanishing cross-correlation functions between component of the linear and angular velocities for SPC/E water have been determined. We have used them to analyze the dynamics of coupled rotational translational motions in this liquid and have examined how this motion is manifest in its local structure. The dominant low-frequency modes in the power spectra of these cross-correlation functions are found to correspond well with the positions of peaks in the experimental Raman and infrared spectra of water.

引用

页码：596 / 600

页数：5

共 12 条

[1]

[Anonymous], 2005, STRUCTURE PROPERTIES

[2]

[Anonymous], 1987, COMPUTER SIMULATION, DOI DOI 10.2307/2938686

[3] THE MISSING TERM IN EFFECTIVE PAIR POTENTIALS [J].