NON-ADIABATIC PHOTODISSOCIATION DYNAMICS OF BRCL

被引:13
作者
CAO, JY [1 ]
LOOCK, HP [1 ]
QIAN, CXW [1 ]
机构
[1] UNIV VICTORIA, DEPT CHEM, VICTORIA V8W 3P6, BC, CANADA
来源
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1994年 / 72卷 / 03期
关键词
D O I
10.1139/v94-101
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nozzle-cooled BrCl was excited with tunable laser radiation at selected wavelengths between 389 and 500 nm. The chlorine atomic fragments in their Cl*(P-2(1/2)) and Cl(P-2(3/2)) State were stated-selectively probed by resonance-enhanced multiphoton ionization. The branching ratio (Cl*/(Cl + Cl*)) was measured as a function of the excitation wavelength. The relative Cl* yield reaches a maximum at around lambda(phot) = 460 nm. Decomposition of these branching ratios into Cl and Cl* photofragment yield spectra provides insight into the BrCl B-state (II)-I-3(0(+)) non-adiabatic dissociation dynamics. Our results suggest that the dissociation mechanism involves non-adiabatic transitions among 0(+) pial energy curves.
引用
收藏
页码:758 / 761
页数:4
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