MONOALKYLTHALLIUM(III) DERIVATIVES - PREPARATION AND X-RAY CRYSTAL-STRUCTURE OF CYCLOPROPYLBIS(ISOBUTYRATO)THALLIUM(III)

被引：9

作者：

BRADY, F

HENRICK, K

MATTHEWS, RW

机构：

[1] Department of Chemistry, The Polytechnic of North London, London, N7 8DB, Holloway Road

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 165卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)81131-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cyclopropylbis(isobutyrato)thallium(III) has been synthesised and its crystal structure determined. The compound crystallises in the orthorhombic space group Pna21, with a 7.316, b 12.079, c 16.19 Å. Linear polymers are present in which thallium is seven-coordinate. Two types of carboxylate ligands are present; one weakly chelating and the other both chelating and bridging. This structure allows clarification of infrared spectroscopic data, presented for mono- and diorganothallium(III) carboxylates, in the solid state in solution. © 1979.

引用

页码：21 / 30

页数：10

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