BETA-HYDROGEN SECONDARY ISOTOPE EFFECT IN ACYL TRANSFER-REACTIONS - ORIGINS, TEMPERATURE-DEPENDENCE, AND UTILITY AS A PROBE OF TRANSITION-STATE STRUCTURE

被引：46

作者：

KOVACH, IM ^{[1
]}

HOGG, JL ^{[1
]}

RABEN, T ^{[1
]}

HALBERT, K ^{[1
]}

RODGERS, J ^{[1
]}

SCHOWEN, RL ^{[1
]}

机构：

[1] UNIV KANSAS,DEPT CHEM,LAWRENCE,KS 66045

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1980年 / 102卷 / 06期

关键词：

D O I：

10.1021/ja00526a039

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：1991 / 1999

页数：9

共 48 条

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[6] Carter R.E., 1973, ADV PHYS ORG CHEM, V10, P1
[7] THIOHYDANTOINS .12. SECONDARY DEUTERIUM-ISOTOPE EFFECTS IN ACID-CATALYZED AND BASE-CATALYZED HYDROLYSIS OF 1-ACETYL-5,5-DIMETHYL-2-THIOHYDANTOIN
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[8] The functional relation between the constants of the Arrhenius equation.
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[9] THEORY OF ALPHA-KETO ACIDS .22. SECONDARY THERMODYNAMIC AND KINETIC DEUTERIUM ISOTOPE EFFECTS IN NUCLEOPHILIC-ADDITION REACTIONS TO ALPHA-CARBONYL GROUP OF PYRUVAMIDE
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[10] NUCLEOPHILIC ADDITION REACTIONS ON KETONES - ADDITION OF SULFITE ION - PRESENTATION OF HYPERCONJUGATION BY MEASUREMENT OF SECONDARY ISOTOPIC EFFECT OF DEUTERIUM
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[J]. TETRAHEDRON, 1971, 27 (22) : 5539 - &

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