REGIOSPECIFIC, DIASTEREOSPECIFIC AND ENANTIOSPECIFIC NUCLEOPHILIC ADDITIONS TO CHIRAL MONOSUBSTITUTED ALKENE COMPLEXES OF THE FORMULA [ETA-5-C5H5)RE(NO)(PPH3)(H2C=CHR)]+ BF4-

被引：21

作者：

PENG, TS ^{[1
]}

GLADYSZ, JA ^{[1
]}

机构：

[1] UNIV UTAH,DEPT CHEM,SALT LAKE CITY,UT 84112

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 31期

关键词：

D O I：

10.1016/S0040-4039(00)97636-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Monosubstituted alkene complexes [(η5-C5H5)Re(NO)(PPh3)(H2CCHR)]+ BF4- and (CH3)2 CuLi react to give β-branched alkyl complexes (η5-C5H5)Re(NO)(PPh3)(CH2CH(CH3)R) as described in the title. The methyl group adds to the alkene face anti to the rhenium. © 1990.

引用

页码：4417 / 4420

页数：4

共 14 条

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