CATALYTIC WET OXIDATIONS OF PHENOL-CONTAMINATED AND P-CHLOROPHENOL-CONTAMINATED WATERS

被引：48

作者：

CHANG, CMJ ^{[1
]}

LI, SS ^{[1
]}

KO, CM ^{[1
]}

机构：

[1] NATL CHUNGHSING UNIV,DEPT ENVIRONM ENGN,TAICHUNG 402,TAIWAN

来源：

JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY | 1995年 / 64卷 / 03期

关键词：

WET OXIDATION; WASTE-WATER; PHENOLS; KINEMATIC CONSTANT;

D O I：

10.1002/jctb.280640306

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 [微生物学]; 0836 [生物工程]; 090102 [作物遗传育种]; 100705 [微生物与生化药学];

摘要：

The rate constant and activation energy of liquid-phase oxidation, catalyzed by CuSO4 . 5H(2)O, MnO2, and Co2O3, were found for synthesized wastewaters containing 1000 mg dm(-3) phenol and 1500 mg dm(-3) p-chlorophenol, respectively. Among the catalysts, CuSO4 . 5H(2)O was demonstrated to be the most effective in reducing the concentration of phenols in wastewaters. The effects of oxygen flow rates and temperatures on the oxidation efficiency were also discussed. The analysis of total organic carbon on the end products after oxidations showed that the liquid phase contained only 10% of intermediate products. Oxidation at different pH values suggested that phenols could be favourably destroyed in an alkaline medium.

引用

页码：245 / 252

页数：8

共 21 条

[1]

CHANG CJ, 1993, J CHEM TECHNOL BIOT, V57, P355

[2]

MECHANISM OF THE OXIDATION OF AQUEOUS PHENOL WITH DISSOLVED-OXYGEN [J].

DEVLIN, HR ;

HARRIS, IJ .

INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1984, 23 (04) :387-392

[3]

HARRIS MT, 1983, US DOE83014214, P1

[4]

Himmelblau D, 1960, CHEM ENG DATA SER

[5]

WET OXIDATION OF WATER-SOLUBLE POLYMERS [J].

IMAMURA, S ;

TONOMURA, Y ;

KAWABATA, N ;

KITAO, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1981, 54 (05) :1548-1553

[6]

WET OXIDATION OF AMMONIA CATALYZED BY CERIUM-BASED COMPOSITE OXIDES [J].

IMAMURA, S ;

DOI, A ;

ISHIDA, S .

INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1985, 24 (01) :75-80

[7]

WET OXIDATION OF POLY(ETHYLENE GLYCOL) CATALYZED BY MANGANESE CERIUM COMPOSITE OXIDE [J].

IMAMURA, S ;

NAKAMURA, M ;

KAWABATA, N ;

YOSHIDA, J ;

ISHIDA, S .

INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1986, 25 (01) :34-37

[8]

WET OXIDATION OF OXYGEN-CONTAINING AND NITROGEN-CONTAINING ORGANIC-COMPOUNDS CATALYZED BY COBALT(III) OXIDE [J].

ITO, MM ;

AKITA, K ;

INOUE, H .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1989, 28 (07) :894-899

[9]

KINETICS OF WET AIR OXIDATION OF PHENOL AND SUBSTITUTED PHENOLS [J].

JOGLEKAR, HS ;

SAMANT, SD ;

JOSHI, JB .

WATER RESEARCH, 1991, 25 (02) :135-145

[10]

WET AIR OXIDATION OF TOXIC INDUSTRIAL EFFLUENTS [J].

KALMAN, J ;

IZSAKI, Z ;

KOVACS, L ;

GROFCSIK, A ;

SZEBENYI, I .

WATER SCIENCE AND TECHNOLOGY, 1989, 21 (4-5) :289-295

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