EPOXIDATION OF OLEFINS USING A CRO3/TBHP SYSTEM

被引：15

作者：

AGARWAL, DD

SRIVASTAVA, S

CHADHA, P

机构：

[1] School of Studies in Chemistry, Jiwaji University

来源：

POLYHEDRON | 1990年 / 9卷 / 04期

关键词：

D O I：

10.1016/S0277-5387(00)86222-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The epoxidation of cyclohexene using CrO3/TBHP gave cyclohexene oxide, cyclohexenol and cyclohexenone in the ratio 3:1:40. The nature of the solvent affects the yield of the product. Pyridine, imidazole, NaH2PO4 and surfactants were found to have negative effects on the yield of epoxide while sodium bicarbonate increases the yield of the epoxide. The relative rate of epoxidation of cyclic olefins was norbornene > cycloheptene > cyclooctene > cyclopentene > cyclohexene. © 1990.

引用

页码：487 / 489

页数：3

共 19 条

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