SECONDARY MOLD METABOLITES .31. ISOLATION AND STRUCTURE ELUCIDATION OF ILLUDINS-A AND ILLUDINS-B, AND ILLUDALENOL, NEW SESQUITERPENOIDS FROM CLITOCYBE-ILLUDENS

被引：31

作者：

ARNONE, A

CARDILLO, R

NASINI, G

DEPAVA, OV

机构：

[1] Dipartimento di Chimica del Politecnico, Centro del C.N.R. per le Sostanze Organiche Naturali, Politecnico di Milano, I 20133 Milano

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1991年 / 04期

关键词：

D O I：

10.1039/p19910000733

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The structure and relative configuration of the three novel sesquiterpenes illudin A 4, illudin B 5 and illudalenol 6, which were isolated from cultures of Clitocybe illudens ( = Omphalotus olearius), have been determined on the basis of H-1 NMR, C-13 NMR and 2D NMR (H-1-C-13 HETCOR and H-1-C-13 COLOC) studies to be (2S*, 4S*)-2,4-dihydroxyillud-5(9)-en-1-one, (2R*, 4S*, 6S*, 8R*)-2,4,6,8-tetrahydroxyillud-5(9)-en-1-one and 4,12-dihydroxyilludala-2,5(9)-dien-1-one, respectively.

引用

页码：733 / 737

页数：5

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