NOVEL CALIXARENES IN THIN-FILMS FOR EFFICIENT 2ND-HARMONIC GENERATION

被引：23

作者：

HEESINK, GJT ^{[1
]}

VANHULST, NF ^{[1
]}

BOLGER, B ^{[1
]}

KELDERMAN, E ^{[1
]}

ENGBERSEN, JFJ ^{[1
]}

VERBOOM, W ^{[1
]}

REINHOUDT, DN ^{[1
]}

机构：

[1] UNIV TWENTE,FAC CHEM TECHNOL,ORGAN CHEM LAB,7500 AE ENSCHEDE,NETHERLANDS

来源：

APPLIED PHYSICS LETTERS | 1993年 / 62卷 / 17期

关键词：

D O I：

10.1063/1.109520

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

Calix[4]arenes are a novel type of molecules for nonlinear optics. In a single molecule four pi-conjugated systems are combined. Corona poled guest-host polymer systems [calix[4]arenes-poly(methyl-methacrylate)] with transparency into the UV and loading up to 100% show a high degree of orientation. The maximum resonant d33 nonlinear coefficient measured at a fundamental wavelength of 590 nm is 51 pm/V. The d33 values of the thin films relax after poling to 65% of their maximum value. Results indicate self-organization of the molecules upon poling.

引用

页码：2015 / 2017

页数：3

共 9 条

[1] NOVEL 2ND-ORDER NONLINEAR OPTICAL POLYMERS VIA CHEMICAL CROSS-LINKING-INDUCED VITRIFICATION UNDER ELECTRIC-FIELD
EICH, M
RECK, B
YOON, DY
WILLSON, CG
BJORKLUND, GC
[J]. JOURNAL OF APPLIED PHYSICS, 1989, 66 (07) : 3241 - 3247
[2] KELDERMAN E, 1992, ANGEW CHEM INT EDIT, V31, P1075, DOI 10.1002/anie.199210751
[3] OPTICAL SECOND-HARMONIC GENERATION BY ELECTRICALLY POLARIZED ISOTROPIC MEDIA
KIELICH, S
[J]. IEEE JOURNAL OF QUANTUM ELECTRONICS, 1969, QE 5 (12) : 562 - &
[4] 2ND-HARMONIC GENERATION AND ABSORPTION STUDIES OF POLYMER DYE FILMS ORIENTED BY CORONA-ONSET POLING AT ELEVATED-TEMPERATURES
MORTAZAVI, MA
KNOESEN, A
KOWEL, ST
HIGGINS, BG
DIENES, A
[J]. JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1989, 6 (04) : 733 - 741
[5] SIMPLE APPROXIMATE TREATMENT OF UNIPOLAR SPACE-CHARGE-DOMINATED CORONAS - THE WARBURG LAW AND THE SATURATION CURRENT
SIGMOND, RS
[J]. JOURNAL OF APPLIED PHYSICS, 1982, 53 (02) : 891 - 898
[6] ELECTRO-OPTIC PHASE MODULATION AND OPTICAL 2ND-HARMONIC GENERATION IN CORONA-POLED POLYMER-FILMS
SINGER, KD
KUZYK, MG
HOLLAND, WR
SOHN, JE
LALAMA, SJ
COMIZZOLI, RB
KATZ, HE
SCHILLING, ML
[J]. APPLIED PHYSICS LETTERS, 1988, 53 (19) : 1800 - 1802
[7] 2ND-ORDER NONLINEAR-OPTICAL PROCESSES IN ORIENTATIONALLY ORDERED MATERIALS - RELATIONSHIP BETWEEN MOLECULAR AND MACROSCOPIC PROPERTIES
SINGER, KD
KUZYK, MG
SOHN, JE
[J]. JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1987, 4 (06) : 968 - 976
[8] STARING EGJ, 1991, RECL TRAV CHIM PAY B, V110, P492
[9] NONLINEAR OPTICAL-PROPERTIES OF POLYMERIC MATERIALS
WILLAND, CS
WILLIAMS, DJ
[J]. BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1987, 91 (11): : 1304 - 1310

← 1 →