DIRECT METAL-METAL BONDS BETWEEN HIGH AND LOW-VALENT COMPLEX FRAGMENTS - THE REACTION OF METAL BASES WITH THE METAL ACIDS [RE(NR)(3)](+) AND [MO(NR)(2)](2+)

被引：17

作者：

SUNDERMEYER, J ^{[1
]}

RUNGE, D ^{[1
]}

FIELD, JS ^{[1
]}

机构：

[1] UNIV NATAL,DEPT CHEM & CHEM TECHNOL,PIETERMARITZBURG 3200,SOUTH AFRICA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 06期

关键词：

D O I：

10.1002/anie.199406781

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Shortened metal–metal bonds caused by electrostatic attraction within the dipolar (metalδ+ – metalδ−) structural unit were observed in the heterobi‐ and heterotrimetallic complexes of type 1 and 2. These complexes were synthesized from the imido complexes [(NtBu)3ReCl] or [(NtBu)2MoCl2] and the carbonyl metalates K[M]. [M] = CpMo(CO)3, CpW(CO)3, Mn(CO)5, CpFe(CO)2, Co(CO)4. (Formula Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：678 / 681

页数：4

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