BINARY COPOLYMERIZATIONS OF FURFURYL METHACRYLATE WITH STYRENE, P-METHYLSTYRENE AND ACRYLONITRILE

被引：4

作者：

GOH, SH

LEE, SY

TAN, CTY

机构：

[1] Department of Chemistry, National University of Singapore, Singapore

来源：

EUROPEAN POLYMER JOURNAL | 1994年 / 30卷 / 04期

关键词：

D O I：

10.1016/0014-3057(94)90049-3

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Furfuryl methacrylate (FMA) was copolymerized with styrene (S), p-methylstyrene (MS) and acrylonitrile (AN). Using the Kelen-Tudos method, the monomer reactivity ratios were found to be r(s) = 0.34 and r(FMA) = 0.42 for S/FMA system, r(MS) = 0.27 and r(FMA) = 0.30 for MS/FMA system, and r(AN) = 0.16 and r(FMA) = 1.60 for AN/FMA system. The copolymerization behaviour of FMA is similar to that of tetrahydrofurfuryl methacrylate. The thermal stabilities of various copolymers were evaluated by thermogravimetry. Incorporation of S, MS or AN improves the thermal stability.

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页码：489 / 494

页数：6

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