FIRST INTRAMOLECULAR BENZYNE DIELS-ALDER REACTION WITH AN ACYCLIC DIENE - UNUSUAL EFFECT OF DIENE GEOMETRY ON THE COURSE OF THE REACTION

被引：18

作者：

BUSZEK, KR

机构：

[1] Department of Chemistry, Kansas State University, Manhattan

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 50期

关键词：

D O I：

10.1016/0040-4039(95)01980-V

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first intramolecular benzyme Diels-Alder reaction with on acyclic diene is reported. The course of the reaction is dependent on the diene geometry. Trans dienes afford [4+2] cycloadducts; cis dienes apparently give [2+2] cycloadduccts followed by further rearrangement, a mechanistic course which is supported by deuterium labeling experiments.

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收藏

页码：9125 / 9128

页数：4

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