ANOMALOUS DOUBLE CYCLIZATION REACTIONS OF BETA-FORMYLPORPHYRINS

被引：80

作者：

BARLOY, L

DOLPHIN, D

DUPRE, D

WIJESEKERA, TP

机构：

[1] Department of Chemistry, University of British Columbia, Vancouver, British Columbia, V6T 1Z1

[2] ULP-Institut Le Bel, Laboratoire de Chimie des M'etaux de transition et de catalyse - U.R.A. 424 C.N.R.S., F 67070 Strasbourg Cedex, 4, rue Blaise Pascal

[3] Research & Development Department, Sun Company Inc., PA 19061, P.O. Box 1135, Marcus Hook

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 26期

关键词：

D O I：

10.1021/jo00105a011

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of nickel(II) and copper(II) complexes of 2(beta)-formyl-meso-tetraphenylporphyrins with strong acid results in intramolecular cyclization involving the carbonyl carbon and the ortho-phenyl position leading to naphthoporphyrin derivatives. However, when electron-releasing groups are present at the m-phenyl positions, a second cyclization occurs involving the 3(beta) position and the ortho position of the adjacent phenyl ring to give an additional fused ring.

引用

页码：7976 / 7985

页数：10

共 23 条

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