EFFECT OF SOLVENTS ON ANION STRUCTURE

被引：34

作者：

KERBER, RC

PORTER, A

机构：

[1] Department of Chemistry, State University of New York at Stony Brook, Stony Brook

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 02期

关键词：

D O I：

10.1021/ja01030a027

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The nmr and electronic spectra of salts of 1-nitroindene and 9-nitrofluorene show significant changes between hydroxylic and nonhydroxylic solvents. These changes demonstrate that hydrogen bonding to the oxygens of the anions tends to localize the charge on the oxygens, and thereby causes alterations in the structure of the anions. Cation coordination to the oxygens in nonpolar aprotic solvents produces similar effects, but of smaller magnitude. Analogous effects are observed for some phenoxide salts. © 1969, American Chemical Society. All rights reserved.

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页码：366 / &

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