INTRAMOLECULAR (3 + 2) CYCLOADDITIONS

被引：5

作者：

COLLINS, MP

MANN, J

CAPPS, N

FINCH, H

机构：

[1] UNIV READING,DEPT CHEM,READING RG6 2AD,BERKS,ENGLAND

[2] GLAXO GRP RES LTD,WARE SG12 0DJ,HERTS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1991年 / 01期

关键词：

D O I：

10.1039/p19910000239

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1-(1-Hydroxy-2-trimethylsilylmethylprop-2-enyl)-2-(4-methoxybut-3enyl)-4-methoxybenzene, prepared by a short synthesis, underwent (3 + 2) cycloaddition to form predominantly the cis-fused tricycle 3,7-dimethoxy-1-methylene-2,3,3a,4,5,9b-hexhydro-1H-benz[e]indene upon treatment with TiCl4 or triflic anhydride.

引用

收藏

页码：239 / 240

页数：2

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