AN ALUMINAPHOSPHACUBANE, A NEW ALUMINUM PHOSPHIDE PRECURSOR

被引：56

作者：

COWLEY, AH

JONES, RA

MARDONES, MA

ATWOOD, JL

BOTT, SG

机构：

[1] UNIV TEXAS,DEPT CHEM,AUSTIN,TX 78712

[2] UNIV ALABAMA,DEPT CHEM,TUSCALOOSA,AL 35486

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 12期

关键词：

D O I：

10.1002/anie.199014091

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Al4P4 cube in [iBuAl(mu-3-PSiPh3)]4 is not only aesthetically attractive. Its behavior on thermal loading makes it also of interest as precursor for the III/V semiconductor AIP. Already at 150-degrees-C the substituents are split off as Ph3SiH and isobutene. Elevation of the temperature to 500-degrees-C leads to pure AIP.

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页码：1409 / 1410

页数：2

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