THE DINUCLEAR PALLADIUM(II) COMPLEX OF PYRIDINE-2-THIOL - SYNTHESIS, STRUCTURE, AND ELECTROCHEMISTRY

被引：108

作者：

UMAKOSHI, K ^{[1
]}

ICHIMURA, A ^{[1
]}

KINOSHITA, I ^{[1
]}

OOI, S ^{[1
]}

机构：

[1] OSAKA CITY UNIV,FAC SCI,DEPT CHEM,OSAKA 558,JAPAN

来源：

INORGANIC CHEMISTRY | 1990年 / 29卷 / 20期

关键词：

D O I：

10.1021/ic00345a019

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of pyridine-2-thiol (pytH) with Pd3(CH3COO)6gives [Pd2(pyt)4] (1), but that with PdCl2(CH3CN)2gives [Pd(pytH)4]Cl2(2), the alkalization of which yields 1. Reaction of 1 with iodine yields neither a dinuclear PdIIPdIIInor PdIIIPdIIIcomplex but tetranuclear [Pd4I2(pyt)6] (3). The structures 1–3 have been investigated by X-ray crystallography. Two Pd atoms in 1 are bridged by four pyt ligands in such way that two cis-PdS2N2units centrosymmetrically face each other. The Pd⋯ distance is 2.677. © 1990, American Chemical Society. All rights reserved.

引用

页码：4005 / 4010

页数：6

共 19 条

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