THE ROLE OF TIN IN LI/SN/MGO CATALYSTS FOR THE OXIDATIVE COUPLING OF METHANE

被引：19

作者：

VANKEULEN, ANJ ^{[1
]}

HOOGENDAM, GC ^{[1
]}

SESHAN, K ^{[1
]}

VANOMMEN, JG ^{[1
]}

ROSS, JRH ^{[1
]}

机构：

[1] TWENTE UNIV TECHNOL,7500 AE ENSCHEDE,NETHERLANDS

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 21期

关键词：

D O I：

10.1039/c39920001546

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The addition of SnO2 to the Li/MgO catalyst system has been found to stabilize its catalytic activity for the oxidative coupling of methane, and, when a large amount of SnO2 is added, a new phase, Li2Mg3SnO6 is identified; pure Li2Mg3SnO6 is also an active and selective catalyst for the oxidative coupling of methane, and in contrast with Li/MgO, it retains lithium under reaction conditions, thereby suppressing deactivation.

引用

页码：1546 / 1547

页数：2

共 7 条

[1]

CHABAN NG, 1985, ZH NEORG KHIM+, V30, P2922

[2]

HAUCK J, 1970, Z NATURFORSCH PT B, VB 25, P109

[3] OXIDATIVE DIMERIZATION OF METHANE OVER A LITHIUM-PROMOTED MAGNESIUM-OXIDE CATALYST [J].