FILMS OF POLY(PYRROLE-[RUII(BPY)2CL2]) - THEIR TRANSFORMATIONS INTO FILMS CONTAINING CIS-[RU11(BPY)2(H2O)2]2+ OR TRANS-[RUII(BPY)2(H2O)2]2+, [RUII(BPY)2(MECN)2]2+ AND [(RUIII(BPY)2(H2O))IO]4+ COMPLEXES, APPLICATION TO ELECTROCATALYSIS (BPY = 2,2'-BIPYRIDINE)

被引：29

作者：

DEGIOVANI, WF ^{[1
]}

DERONZIER, A ^{[1
]}

机构：

[1] UNIV GRENOBLE 1,ELECTROCHIM ORGAN & PHOTOCHIM REDOX LAB,CNRS,URA 1210,BP 53X,F-38041 GRENOBLE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 19期

关键词：

D O I：

10.1039/c39920001461

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A ruthenium(II) bis(chloro) complex containing two 2,2'-bipyridine (bpy) ligands substituted with pyrrole groups has been synthesized and anodically electropolymerized on platinum, glassy carbon or SnO2 electrodes; [RuII(bpy)2Cl2] sites in the polymer are readily converted into other ruthenium complexes as cis- or trans-[Ru(bpy)2(H2O)2]2+, [{Ru(bpy)2(H2O)}2O]4+ and [Ru(bpy)2(MeCN)2]2+ and the capability of the polypyrrole cis-[Ru(bpy)2(H2O)2]2+ films to act as an electrocatalyst has been tested.

引用

页码：1461 / 1463

页数：3

共 13 条

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