HYDRIDE TO CARBENE MIGRATIONS

[1] SYNTHESES AND REACTIONS OF ACYCLIC AND CYCLIC CARBENE COMPLEXES CIS-[MI(=CMENHME)(CO)2(ETA-C5H5)](M=MO OR W) AND CIS-[MI(=C(CH2)NNME)(CO)2(ETA-C5H5)](M=MO,N=3 OR 4-M=W,N=3) OBTAINED THROUGH ALKYL MIGRATION TO METHYL ISOCYANIDE COORDINATED TO MOLYBDENUM OR TUNGSTEN - X-RAY STRUCTURE OF CIS-[MOI(=C(CH2)3NME)-(CO)2(ETA-C5H5)]O [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (10): : 2127 - 2135

[2] REACTIONS OF THE METALLABROMOALKANE [MO((CH2)3BR)(CO)3(ETA-C5H5)] AND THE CARBENE COMPLEXES TRANS-[MOI(=C(CH2)3O)(CO)2(ETA-C5H4R)](R=H OR ME) WITH LI(BET3H) - THE SYNTHESIS (R=H OR ME) AND X-RAY STRUCTURE (R=ME) OF [MO(CH(CH2)3O)(CO)2(ETA-C5H4R)] CONTAINING AN UNUSUAL OXYGEN MOLYBDENUM DONOR INTERACTIONH [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (10): : 2119 - 2126

[3] ADAMS H, IN PRESS

[4] CRYSTAL AND MOLECULAR-STRUCTURE OF A DIOXO-MOLYBDENUM PHOSPHORUS-SUBSTITUTED ALKYLIDENE RESULTING FROM THE 1ST OBSERVED ARYL MIGRATION FROM MOLYBDENUM TO CARBON [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (17) : 1151 - 1152

[5] CYCLIC CARBENE COMPLEXES OF MOLYBDENUM AND TUNGSTEN - CRYSTAL AND MOLECULAR-STRUCTURE OF [MOL(CO)2(CO(CH2)2CH2)(ETA-C5H5)] [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (11): : 2397 - 2403

[6] PENTAMETHYLCYCLOPENTADIENYL MOLYBDENUM AND TUNGSTEN CARBENE COMPLEXES - X-RAY CRYSTAL-STRUCTURES OF CIS-[MOL(CO)2(=C(CH2)3O)(ETA-C5ME5)] AND TRANS-[MOL(CO)2(=C(CH2)3O)(ETA-C5ME5)] [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (06): : 1449 - 1456

[7] REACTIVITY OF BIS(PENTAMETHYLCYCLOPENTADIENYL)ZIRCONIUM HYDRIDES WITH GROUP-8 TRANSITION-METAL CARBONYLS [J]. ORGANOMETALLICS, 1984, 3 (02) : 278 - 284

[8] SYNTHESES AND REACTIONS OF LM(SNPH3)(CO)2(=C(OET)PH) (L=C5ME5 OR ETA-5-C9H7, M=MO OR W) [J]. POLYHEDRON, 1989, 8 (13-14) : 1861 - 1862

[9] CASEY CP, 1971, J CHEM SOC CHEM COMM, P1220

[10] SYNTHESIS, STRUCTURE AND REACTIONS OF A DIHAPTO-FORMALDEHYDE COMPLEX, OS(ETA-2-CH2O)(CO)2(PPH3)2 [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 231 (04) : 335 - 360

[1] SYNTHESES AND REACTIONS OF ACYCLIC AND CYCLIC CARBENE COMPLEXES CIS-[MI(=CMENHME)(CO)2(ETA-C5H5)](M=MO OR W) AND CIS-[MI(=C(CH2)NNME)(CO)2(ETA-C5H5)](M=MO,N=3 OR 4-M=W,N=3) OBTAINED THROUGH ALKYL MIGRATION TO METHYL ISOCYANIDE COORDINATED TO MOLYBDENUM OR TUNGSTEN - X-RAY STRUCTURE OF CIS-[MOI(=C(CH2)3NME)-(CO)2(ETA-C5H5)]O [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (10): : 2127 - 2135

[2] REACTIONS OF THE METALLABROMOALKANE [MO((CH2)3BR)(CO)3(ETA-C5H5)] AND THE CARBENE COMPLEXES TRANS-[MOI(=C(CH2)3O)(CO)2(ETA-C5H4R)](R=H OR ME) WITH LI(BET3H) - THE SYNTHESIS (R=H OR ME) AND X-RAY STRUCTURE (R=ME) OF [MO(CH(CH2)3O)(CO)2(ETA-C5H4R)] CONTAINING AN UNUSUAL OXYGEN MOLYBDENUM DONOR INTERACTIONH [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (10): : 2119 - 2126

[3] ADAMS H, IN PRESS

[4] CRYSTAL AND MOLECULAR-STRUCTURE OF A DIOXO-MOLYBDENUM PHOSPHORUS-SUBSTITUTED ALKYLIDENE RESULTING FROM THE 1ST OBSERVED ARYL MIGRATION FROM MOLYBDENUM TO CARBON [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (17) : 1151 - 1152

[5] CYCLIC CARBENE COMPLEXES OF MOLYBDENUM AND TUNGSTEN - CRYSTAL AND MOLECULAR-STRUCTURE OF [MOL(CO)2(CO(CH2)2CH2)(ETA-C5H5)] [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (11): : 2397 - 2403

[6] PENTAMETHYLCYCLOPENTADIENYL MOLYBDENUM AND TUNGSTEN CARBENE COMPLEXES - X-RAY CRYSTAL-STRUCTURES OF CIS-[MOL(CO)2(=C(CH2)3O)(ETA-C5ME5)] AND TRANS-[MOL(CO)2(=C(CH2)3O)(ETA-C5ME5)] [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (06): : 1449 - 1456

[7] REACTIVITY OF BIS(PENTAMETHYLCYCLOPENTADIENYL)ZIRCONIUM HYDRIDES WITH GROUP-8 TRANSITION-METAL CARBONYLS [J]. ORGANOMETALLICS, 1984, 3 (02) : 278 - 284

[8] SYNTHESES AND REACTIONS OF LM(SNPH3)(CO)2(=C(OET)PH) (L=C5ME5 OR ETA-5-C9H7, M=MO OR W) [J]. POLYHEDRON, 1989, 8 (13-14) : 1861 - 1862

[9] CASEY CP, 1971, J CHEM SOC CHEM COMM, P1220

[10] SYNTHESIS, STRUCTURE AND REACTIONS OF A DIHAPTO-FORMALDEHYDE COMPLEX, OS(ETA-2-CH2O)(CO)2(PPH3)2 [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 231 (04) : 335 - 360