REACTIVITY AND SELECTIVITY IN LEWIS-ACID-CATALYZED DIELS-ALDER REACTIONS OF 2-CYCLOHEXENONES

被引：32

作者：

FRINGUELLI, F ^{[1
]}

MINUTI, L ^{[1
]}

PIZZO, F ^{[1
]}

TATICCHI, A ^{[1
]}

机构：

[1] UNIV PERUGIA,DIPARTIMENTO CHIM,VIA ELCE SOTTO 8,I-06100 PERUGIA,ITALY

来源：

ACTA CHEMICA SCANDINAVICA | 1993年 / 47卷 / 03期

关键词：

D O I：

10.3891/acta.chem.scand.47-0255

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The reactivity, regioselectivity, endo-exo diastereoselectivity and diastereofacial selectivity of the Lewis-acid-catalyzed Diels-Alder reactions of 2-cyclohexenones are discussed. The syn-anti diastereofacial selectivity of the cycloadditions is interpreted in terms of a unifying stereoelectronic pathway and conformational effects.

引用

页码：255 / 263

页数：9

共 54 条

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