ELECTRICAL-PROPERTIES OF M(S2C2(CN)2)21-(M = NI, PT) COMPLEXES

被引：10

作者：

MILLER, JS ^{[1
]}

EPSTEIN, AJ ^{[1
]}

机构：

[1] XEROX CORP,WEBSTER RES CTR,ROCHESTER,NY 14644

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1979年 / 8卷 / 04期

关键词：

D O I：

10.1080/00958977908076496

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Single crystal conductivity studies over a temperature range of 200° K to 400° K have been carried out on various M(S2C2(CN)2)21-(M=Ni, Pt) salts. A room temperature conductivity of ~ 10-10 ohm-1 cm-1 and an Ea ≅ 0.5 eV was observed for each of these systems. These results are correlated with the magnetic, electronic, and crystallographic properties. The semiconducting behavior of these systems is related to the electronic structure of the molecular anion. © 1979, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：191 / 194

页数：4

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