SOME COBALT(III) COMPLEXES WITH COORDINATED DIOXYGEN AND MULTI-DENTATE AND CYCLIC AMINE LIGANDS

被引：20

作者：

LAWRANCE, GA

LAY, PA

机构：

[1] Department of Inorganic Chemistry, University of Melbourne, Parkville

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1979年 / 41卷 / 03期

关键词：

D O I：

10.1016/0022-1902(79)80137-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Syntheses of ten binuclear μ-peroxo cobalt(III) complexes with coordinated cyclic tetraamines 5,7-dimethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene and 5,7,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene or chelated diamines and triamines are reported. Absorption maxima of the μ-peroxo and of three μ-superoxo binuclear complexes generated in solution are tabulated. ESR solution spectra of the μ-superoxo binuclear complexes and of a new mononuclear superoxo complex of the cyclic tetraamine rac-5,7,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane are presented. © 1979.

引用

页码：301 / 304

页数：4

共 26 条

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