AMPHIPHILIC PROPANE-1,2-DIOL DERIVATIVES INCORPORATING CALAMITIC STRUCTURAL UNITS

被引：19

作者：

TSCHIERSKE, C

LUNOW, A

JOACHIMI, D

HENTRICH, F

GIRDZIUNAITE, D

ZASCHKE, H

MADICKE, A

BREZESINSKI, G

KUSCHEL, F

机构：

[1] Martin-Luther-Universitat Halle-Wittenberg, Sektion Chemie, Halle

来源：

LIQUID CRYSTALS | 1991年 / 9卷 / 06期

关键词：

D O I：

10.1080/02678299108055004

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel amphiphilic propane-1,2-diol derivatives incorporating a wide variety of calamitic structural units, like biphenyl, dicyclohexyl, phenylbenzoate, phenylpyrimidine and phenylthiadiazole, were synthesized and their mesomorphic behaviour studied. Most of these compounds exhibit broad smectic A and C mesophases in the water-free state. These mesophases could be stabilized further by addition of water. The transition temperatures depend mainly on the hydrophilic properties of the rigid core and on the length of the spacer by which the core is connected to the diol unit.

引用

页码：821 / 829

页数：9

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