PREPARATION OF ENANTIOMERICALLY ENRICHED COMPOUNDS BY USING ENZYMES .10. BIOCHEMICAL PREPARATION OF OPTICALLY-ACTIVE 4-HYDROXY-BETA-IONONE AND ITS TRANSFORMATION TO (S)-6-HYDROXY-ALPHA-IONONE

被引：19

作者：

KAKEYA, H ^{[1
]}

SUGAI, T ^{[1
]}

OHTA, H ^{[1
]}

机构：

[1] KEIO UNIV,DEPT CHEM,HIYOSHI 3-14-1,KOHOKU KU,YOKOHAMA,KANAGAWA 223,JAPAN

来源：

AGRICULTURAL AND BIOLOGICAL CHEMISTRY | 1991年 / 55卷 / 07期

关键词：

D O I：

10.1080/00021369.1991.10870844

中图分类号：

S3 [农学（农艺学）];

学科分类号：

0901 ;

摘要：

The preparation of 4-hydroxy-beta-ionone of high enantiomeric excess was achieved via lipase-catalyzed transesterification of the corresponding racemate as the key-step. Starting from Its (R)-enantiomer, (S)-6-hydroxy-alpha-ionone, an important intermediate for synthetic abscisic acid analogs, was synthesized.

引用

页码：1873 / 1876

页数：4

共 14 条

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