IMPACT OF THE ADSORBATE COMPRESSIBILITY ON THE CALCULATION OF THE MICROPORE VOLUME

被引：20

作者：

DUBININ, MM ^{[1
]}

NEIMARK, AV ^{[1
]}

SERPINSKY, VV ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,INST PHYS CHEM,MOSCOW 117915,RUSSIA

来源：

CARBON | 1993年 / 31卷 / 07期

关键词：

ADSORPTION; MICROPORES; ACTIVATED CARBON; PORE VOLUME; COMPRESSIBILITY; DUBININ RADUSHKEVICH THEORY;

D O I：

10.1016/0008-6223(93)90051-B

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The theory of micropore volume filling has been modified in taking into account the adsorbate compressibility. A new equation has been obtained for calculating the micropore volume from the experimental value of the limit of adsorption. The estimations, with the example of benzene adsorption on activated carbons, show that because of the adsorbate compressibility, the real micropore volume can exceed the values calculated from the conventional Dubinin-Radushkevich theory by about 10% at room temperature, and this difference increases with an increase in temperature.

引用

页码：1015 / 1018

页数：4

共 8 条

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[2]

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