ACTION OF PERIODIC ACID AND ITS SALTS ON WOOL .2. AMINO ACIDS IN PERIODATE-OXIDIZED WOOL

被引:4
作者
KANTOUCH, A
BENDAK, A
机构
[1] National Research Centre, Textile Research Laboratory, Dokki, Cairo
关键词
Amino Acids; Chromatography; Concentration; Cystine; Hydrolysis; Infrared Spectroscopy; Merino Wool; Oxidation; Periodates; pH; Rate; Reactions (Chemical); Solutions; Sorption; Sulfur Compounds; Sulfuric Acid; Tryptophan; Tyrosine; Wools;
D O I
10.1177/004051756903900908
中图分类号
TB3 [工程材料学]; TS1 [纺织工业、染整工业];
学科分类号
0805 ; 080502 ; 0821 ;
摘要
In the present work, the amino acid content of periodate-oxidized wool is investigated. In general, amino acids in periodate-oxidized wool decrease to different degrees depending on their difference in reactivity. The controlling factor for the change of amino acids in periodate-oxidized wool is the periodate consumption, regardless of the reaction conditions. At a periodate consumption of 2.5 mmole/g wool, a decrease in amino acids ranging from 3% for arginine to 70% for serine and tryptophan is observed. The change in amino acids in wool is also discussed on the basis of organic reactions, and, by analogy, with reaction of periodate with free amino acids and peptides. © 1969, SAGE Publications. All rights reserved.
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页码:851 / &
相关论文
共 36 条
[1]   THE REACTION OF OXIDIZING AGENTS WITH WOOL .5. THE OXIDATION PRODUCTS OF THE DISULPHIDE BOND AND THE FORMATION OF A SULPHONAMIDE IN THE PEPTIDE CHAIN [J].
ALEXANDER, P ;
FOX, M ;
HUDSON, RF .
BIOCHEMICAL JOURNAL, 1951, 49 (02) :129-138
[2]   ON THE OXIDATION OF NON-HYDROXYAMINO ACIDS BY PERIODIC ACID [J].
ARAKAWA, K .
JOURNAL OF BIOCHEMISTRY, 1957, 44 (04) :217-225
[3]   Oxidative cleavage of alpha-keto acids and alpha-keto alcohols by means of lead tetraacetate [J].
Baer, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1940, 62 :1597-1606
[4]  
BAUTERS M, 1959, BULL ITF, V80, P7
[5]  
BELLAMY LJ, 1958, INFRARED SPECTRA COM, P156
[6]   OXIDATION OF TRYPTOPHAN AND SOME RELATED COMPOUNDS WITH PERSULPHATE [J].
BOYLAND, E ;
SIMS, P ;
WILLIAMS, DC .
BIOCHEMICAL JOURNAL, 1956, 62 (04) :546-550
[7]   The reaction of periodic acid with alpha-ketols, alpha-diketones, and alpha-ketonealdehydes. [J].
Clutterbuck, PW ;
Reuter, F .
JOURNAL OF THE CHEMICAL SOCIETY, 1935, :1467-1469
[8]  
DESNUELLE P, 1947, B SOC CHIM BIOL, V29, P694
[9]   ABSORPTION SPECTRA AND STRUCTURE OF SULPHINIC ACIDS [J].
DETONI, S ;
HADZI, D .
JOURNAL OF THE CHEMICAL SOCIETY, 1955, :3163-3169
[10]  
EVERED DE, 1959, BIOCHIM BIOPHYS ACTA, V34, P14