In order to perform spectral analysis in the thermal infrared bands, temperature-independent thermal infrared spectral indices (TISI) are derived from observable thermal infrared radiances. Being temperature-independent and simply related to spectral emissivities of the observed surface, these indices are as easy to use to perform spectral analysis as reflectances in the visible and near infrared spectral domains. Examples of such indices are given for TIMS and AVHRR. Several properties of these indices are discussed, particularly their sensitivity to spectral emissivity variation, their efficient combination, and the derivation of relative spectral emissivity. These indices are quite complementary to NDVI and can lead to stronger results if used together rather than separately. For instance, in the examples worked out, these indices are more sensitive to bare soils characteristics than NDVI. Furthermore, these indices can be tailored to weight certain bands more heavily than others, giving to these indices a wide range of application. They may, for instance, be used for geologic compositional mapping. Practical examples from TIMS and AVHRR data are shown and briefly discussed with a possible applications to the determination from AVHRR data of the surface temperature and surface emissivity. © 1990.