AN IMIDE RADICAL-ANION WHICH ASSEMBLES INTO PI-STACKS IN SOLUTION

被引：20

作者：

PENNEAU, JF ^{[1
]}

MILLER, LL ^{[1
]}

机构：

[1] UNIV MINNESOTA, DEPT CHEM, MINNEAPOLIS, MN 55455 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1991年 / 30卷 / 08期

关键词：

D O I：

10.1002/anie.199109861

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The radical anion 1⊙⊖ is present as a monomer in dimethylformamide, as a dimer in aqueous dimethylformamide, and as stacks in aqueous NaCl solution according to ESR and UV/VIS spectra. The “π stacks” of 1⊙⊖—actually a trianion—are soluble models for conducting organic charge‐transfer compounds. Thin, black, lustrous films of 1⊙⊖ exhibit a conductivity of 0.1 S cm−1. (Figure Presented.) Copyright © 1991 by VCH Verlagsgesellschaft mbH, Germany

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页码：986 / 987

页数：2

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