ON THE RELATIVE REACTIVITY OF CARBONYL AND IMINIUM ION MOIETIES

被引：8

作者：

AGAMI, C

COUTY, F

HAMON, L

PUCHOT, C

机构：

[1] Laboratoire de Chimie Organique Assocé au CNRS, Université Pierre et Marie Curie, 75005 Paris

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 25期

关键词：

D O I：

10.1016/S0040-4039(00)92525-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

AMI calculations. performed on models exhibiting both moieties, show that, in agreement with experimental work, an aldehyde group is more reactive than an iminium ion towards a hard nucleophile.

引用

页码：3645 / 3646

页数：2

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